In the relativistic quantum mechanics of superheavy elements (e.g., Greiner, Müller, Rafelski; and multi-configuration Dirac–Fock calculations by Pyykkö and Fricke), the extended periodic table is predicted to terminate around Z172Z \approx 172 . At this critical charge, the 1s1/21s_{1/2} state dives into the negative-energy Dirac sea ( E1smec2E_{1s} \le -m_e c^2 ), triggering spontaneous positron emission in a supercritical Coulomb field. In the non-relativistic regime, the Madelung ( n+n+\ell ) rule generates period capacities according to the well-known sequence: C(k)=2k+322C(k) = 2 \left\lfloor \frac{k + 3}{2} \right\rfloor^2 yielding the standard progression: 2, 8, 8, 18, 18, 32... The cumulative sum through the 6th period (terminating at Radon, Z=86Z = 86 ) is exactly: k=05C(k)=2+8+8+18+18+32=86\sum_{k=0}^{5} C(k) = 2 + 8 + 8 + 18 + 18 + 32 = 86 Intriguingly, in Pyykkö’s extended Dirac–Fock calculations (2011), the total number of predicted elements between Francium ( Z=87Z = 87 ) and the terminal noble-gas-like closure at Z=172Z = 172 ( 8p3/248p_{3/2}^4 ) is also exactly: 17286=86 elements172 - 86 = 86 \text{ elements} While some extended models predict an expansion into a massive 50-element 8th period (introducing an uncontracted 18-element gg -block), relativistic calculations show severe spin-orbit splitting: 8p1/28p_{1/2} and 9s1/29s_{1/2} states undergo drastic contraction, fundamentally shifting the Aufbau sequence and leading to predictions like a solid-state noble gas at Z=118Z=118 (Oganesson). If one maps the remaining 86 elements under a strictly reversed capacity constraint mirroring the Madelung sequence—defined as Crel(k)=C(11k)C_{\text{rel}}(k) = C(11 - k) —it forms the symmetric 12-tier scheme illustrated below. The 86 non-relativistic elements ( Z=186Z = 1 \dots 86 ) perfectly mirror the 86 relativistic elements ( Z=87172Z = 87 \dots 172 ). What makes this grouping particularly perplexing from a theoretical standpoint is the convergence of two completely decoupled physical mechanisms at the exact same integer Z=172Z = 172 : The Core / QED Scale: The breakdown of neutral atomic existence is dictated by the innermost 1s1/21s_{1/2} state diving into the negative continuum ( Zcr172Z_{\text{cr}} \approx 172 ). This threshold is strictly governed by nuclear volume effects ( RA1/3R \sim A^{1/3} ) and short-range QED vacuum polarization (Uehling potential). The Valence / Chemical Scale: Simultaneously, Z=172Z = 172 is identified by Pyykkö as a formal closed-shell "noble" configuration ( 8p3/248p_{3/2}^4 ). Here, the closing subshell is separated from its spin-orbit partner 8p1/228p_{1/2}^2 (which fills 50\sim 50 elements earlier at Z=121122Z = 121\text{--}122 ) by an unprecedented spin-orbit splitting that spans the entire 8th period. In non-relativistic physics, the period-doubling of the Madelung rule (2, 8, 8, 18, 18, 32, 32) is deeply tied to the dynamical SO(4)SO(4) Fock symmetry of the Coulomb problem (as analyzed in the Demkov–Ostrovsky model). When relativistic Dirac kinematics explicitly break this SO(4)SO(4) symmetry down to central-field jj - jj coupling, one would expect the arithmetic symmetry of the shell capacities to shatter entirely. My questions are: From the perspective of relativistic Dirac–Fock / QED calculations, is there any dynamical mechanism (such as extreme spin-orbit splitting, Darwin terms, or vacuum polarization) that justifies grouping superheavy subshell capacities into a contracting sequence C(11k)C(11 - k) as Z172Z \to 172 ? Is this exact 868686 \leftrightarrow 86 partition strictly a coincidental arithmetic artifact arising from the fact that Pyykkö’s 8p3/248p_{3/2}^4 shell closure happens to occur near the QED critical charge Zcr172Z_{\text{cr}} \approx 172 ? Is there any hidden group-theoretic constraint (perhaps an embedding of the broken SO(4)SO(4) symmetry into a relativistic dynamical group) that forces the total number of bound relativistic states up to the nuclear QED diving limit ( ZcrZ_{\text{cr}} ) to preserve the exact integer dimension of the first six non-relativistic periods ( k=05C(k)=86\sum_{k=0}^{5} C(k) = 86 )? References: P. Pyykkö, A suggested periodic table up to Z172Z \le 172 , based on Dirac–Fock calculations on atoms and ions , Phys. Chem. Chem. Phys. 13, 161–168 (2011). B. Fricke, W. Greiner, J. T. Waber, The continuation of the periodic table up to Z = 172 , Theor. Chim. Acta 21, 235–260 (1971). Yu. N. Demkov, V. N. Ostrovsky, n+n+\ell filling rule in the periodic system and focusing of electrons in a modified Coulomb field , Zh. Eksp. Teor. Fiz. 62, 125–132 (1972).