Suppose we have the following cycle in the diagram for a Van der Waals gas: The internal energy , and equation of state for a VdW gas being: and the heat capacities being linked by the Mayer relation: so one could calculate the coefficients from the equation of state. My textbook says that heat transfered from is: It can be show that is volume independent for a VdW gas but here we assume that is temperature independent , how does one justify that ? Continuing, if we calculate the heat transfered by going from to : but this time is not temperature independent , which makes sense given the various terms in the Mayer relation depend on . Summary: How does one justify being temperature independent for ?
Confusion regarding heat capacity $C_V $ for a Van der Waals gas
lohey

