Suppose we have the following cycle in the PVP-V diagram for a Van der Waals gas: The internal energy , and equation of state for a VdW gas being: U=CVTaN2VU = C_V T- a\dfrac{N^2}{V} P+aN2V2=NkBTVNbP + a\dfrac{N^2}{V^2} = \dfrac{Nk_B T}{V-Nb} and the heat capacities being linked by the Mayer relation: CPCV=TVα2κTC_P - C_V = TV \dfrac{\alpha^{2}}{\kappa_T} so one could calculate the coefficients α,κT\alpha , \kappa_T from the equation of state. My textbook says that heat transfered from ABA \rightarrow B is: QAB=ΔUWAB=0=ABCVdT=CV(T2T1)Q_{AB} = \Delta U - \underbrace{W_{AB}}_\text{$=0$} = \int^B_A C_V dT = C_V (T_2 - T_1) It can be show that CVC_V is volume independent for a VdW gas but here we assume that CVC_V is temperature independent , how does one justify that ? Continuing, if we calculate the heat transfered by going from CC to AA : QCA=ΔUWAC=CACPdTCPΔTQ_{CA} = \Delta U - W_{AC} = \int^A_C C_P dT \neq C_P \Delta T but this time CPC_P is not temperature independent , which makes sense given the various terms in the Mayer relation depend on TT . Summary: How does one justify CVC_V being temperature independent for ABA \rightarrow B ?